Hydrocarbons · NEET Preparation Chemistry

Which of the following reagents can be used to convert an alkyne to a cis-alkene?

Practice question from Hydrocarbons (NEET Preparation Chemistry), with the correct answer and a step-by-step solution.

medium · MCQ · Q-5C400B

Which of the following reagents can be used to convert an alkyne to a cis-alkene?

  1. A.Na in liquid NH3
  2. B.H2 in the presence of Lindlar's catalystCorrect answer
  3. C.Zn/HCl
  4. D.Red phosphorus and HI

Solution

Catalytic hydrogenation of alkynes using Lindlar's catalyst (palladized charcoal deactivated with quinoline or sulfur compounds) gives syn-addition of hydrogen, yielding cis-alkenes. Sodium in liquid NH3 gives trans-alkenes via a dissolving metal reduction.

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