The p-Block Elements · JEE Preparation Chemistry

Which of the following oxoacids of phosphorus contains both -PH and -OH bonds, and is a strong reducing agent?

Practice question from The p-Block Elements (JEE Preparation Chemistry), with the correct answer and a step-by-step solution.

medium · MCQ · Q-E22290

Which of the following oxoacids of phosphorus contains both −PH-PH and −OH-OH bonds, and is a strong reducing agent?

  1. A.H3PO4H_3PO_4
  2. B.H3PO3H_3PO_3Correct answer
  3. C.H4P2O7H_4P_2O_7
  4. D.HPO3HPO_3

Solution

Phosphorous acid (H3PO3H_3PO_3) has the structure H−P(=O)(OH)2H-P(=O)(OH)_2, containing one P−HP-H bond, two P−OHP-OH bonds, and one P=OP=O bond. The hydrogen directly attached to phosphorus is responsible for its strong reducing property.

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