Amines · Class 12 · CBSE · Science Chemistry

The correct order of basicity of aliphatic amines in aqueous solution is:

Practice question from Amines (Class 12 · CBSE · Science Chemistry), with the correct answer and a step-by-step solution.

medium · MCQ · Q-6299D5

The correct order of basicity of aliphatic amines in aqueous solution is:

  1. A.(CH3)3N > (CH3)2NH > CH3NH2 > NH3
  2. B.(CH3)2NH > CH3NH2 > (CH3)3N > NH3
  3. C.(CH3)2NH > (CH3)3N > CH3NH2 > NH3Correct answer
  4. D.CH3NH2 > (CH3)2NH > (CH3)3N > NH3

Solution

In aqueous solution, the basicity of methyl-substituted amines is affected by a combination of inductive effect, solvation effect, and steric hindrance. For methyl groups, the order of basicity is secondary > tertiary > primary > ammonia, i.e., (CH3)2NH>(CH3)3N>CH3NH2>NH3(CH_3)_2NH > (CH_3)_3N > CH_3NH_2 > NH_3.

More from Amines

All of Amines

Practise more Chemistry

Sign up free for adaptive practice on this chapter, with instant feedback and hints on every question.

Start practising free

Free to start · No credit card needed