Equilibrium · NEET Preparation Chemistry

The pH of a 10^{-8} M HCl aqueous solution at 298 K is closest to:

Practice question from Equilibrium (NEET Preparation Chemistry), with the correct answer and a step-by-step solution.

hard · MCQ · Q-76EF7B

The pH of a 10−810^{-8} M HCl aqueous solution at 298 K is closest to:

  1. A.8.0
  2. B.6.98Correct answer
  3. C.7.0
  4. D.10.0

Solution

For an extremely dilute acid solution like 10−810^{-8} M HCl, the contribution of H+H^+ ions from the autoionization of water cannot be neglected. Using the charge neutrality condition [H+]=[Cl−]+[OH−][H^+] = [Cl^-] + [OH^-], let x=[H+]x = [H^+]. Then x=10−8+10−14xx = 10^{-8} + \frac{10^{-14}}{x}. Solving this quadratic equation gives x≈1.051×10−7x \approx 1.051 \times 10^{-7} M, so pH=−log⁡10(1.051×10−7)≈6.98\text{pH} = -\log_{10}(1.051 \times 10^{-7}) \approx 6.98.

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