The d- and f-Block Elements · NEET Preparation Chemistry

Why do transition elements exhibit higher enthalpies of atomization?

Practice question from The d- and f-Block Elements (NEET Preparation Chemistry), with the correct answer and a step-by-step solution.

medium · MCQ · Q-70EC37

Why do transition elements exhibit higher enthalpies of atomization?

  1. A.Due to absence of vacant d-orbitals
  2. B.Due to involvement of a large number of electrons from (n−1)d(n-1)d in addition to nsns electrons in interatomic bondingCorrect answer
  3. C.Due to completely filled dd-orbitals leading to stable configurations
  4. D.Due to very small atomic radii of transition elements

Solution

Transition elements have strong interatomic bonding due to the participation of both nsns and (n−1)d(n-1)d electrons in metallic bonding, which results in a greater number of unpaired electrons available for bonding, hence higher enthalpies of atomization.

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