The d- and f-Block Elements · NEET Preparation Chemistry

The gradual decrease in atomic and ionic radii along the lanthanoid series is known as lanthanoid contraction. This is primarily due to:

Practice question from The d- and f-Block Elements (NEET Preparation Chemistry), with the correct answer and a step-by-step solution.

easy · MCQ · Q-C22F8D

The gradual decrease in atomic and ionic radii along the lanthanoid series is known as lanthanoid contraction. This is primarily due to:

  1. A.Poor shielding of 4f4f electronsCorrect answer
  2. B.Effective shielding of 4f4f electrons
  3. C.Increasing nuclear charge being nullified by 5d5d electrons
  4. D.Decreasing nuclear charge along the series

Solution

As we move along the lanthanoid series, nuclear charge increases by one at each step, while the incoming electron enters the 4f4f orbital. Due to the very poor shielding effect of 4f4f electrons, the effective nuclear charge experienced by the outer electrons increases, pulling the electron cloud closer and causing lanthanoid contraction.

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